Publikationen am Institut für Chemie und Biotechnik

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Lazarenko, Aleksandra; Vovchenko, Lyudmila; Matzui, Lyudmila; Kozachenko, Victor; Prylutskyy, Yuriy; Scharff, Peter; Ritter, Uwe
Thermal diffusivity of nanocarbon composites. - In: Polymer composites, ISSN 1548-0569, Bd. 32 (2011), 1, S. 14-17

This study was performed to measure the thermal diffusivity of different types of nanocarbon composites. Thermoexfoliated graphite (TEG), ultrasonically dispersed TEG, and multiwalled carbon nanotubes were used as fillers in epoxy polymer matrixes. The nanocarbon filler content was 1-10 wt%. The temperature dependence of the thermal conductivity and the heat capacity were extensively characterized in the temperature range between 150 and 425 K. For this purpose, the thermal diffusivity of the composites was investigated by two experimental methods: dynamic A-calorimeter and photoacoustic. The comparative analysis of thermal diffusivity of compacted TEG samples with different densities and of nanocarbon-epoxy with different filler content was carried out. It was found that for the composites with a low distribution of the nanocarbon filler, the thermal diffusivity increases and that the value is determined by the structural and morphological properties of the filler. The orientation function for the TEG-epoxy composites and the compact TEG samples differs due to the epoxy matrix that reduced anisotropy of the composite. POLYM. COMPOS., 2011. (C) 2010 Society of Plastics Engineers



https://doi.org/10.1002/pc.21009
Erismis, Harun; Nemec, Dominik; Geiss, Michael; Skakalova, Viera; Ritter, Uwe; Kolaric, Ivica; Roth, Siegmar
Penetration based CNT/Sol-Gel composite films and their remarkable electrical properties. - In: Microelectronic engineering, Bd. 88 (2011), 8, S. 2513-2525

In this work we present a novel method for CNT/Sol-Gel film preparation, combining low resistivity and improved adhesion behaviour on glass substrates. Naturally occurring voids, with diameters of 50-100 nm, in sprayed CNT networks are used for SolGel penetration via dip coating method. Thermal treatments, for composite film densification, in the range of 200-700 ˚C are investigated and electrical properties were compared to identically treated reference samples with the same batch of nanotubes but without Sol-Gel. The resistivity of such composite films, with best value of similar to 0.03 Omega cm for MWNTs, is two orders of magnitudes lower than previously reported for CNT/Sol-Gel composites. Surprisingly the surface resistance of the composite film shows 25% improvement compared to thermally equal treated pure CNT films. In addition, crosscut adhesion behaviour is investigated, including tape test, showing good performance for composite films, where Sol-Gel acts as an adhesion promoter.



http://dx.doi.org/10.1016/j.mee.2011.01.015
Singh, Sukhdeep; Schober, Andreas; Gebinoga, Michael; Groß, Gregor Alexander
Convenient method for synthesis of thiazolo[3,2-a]pyrimidine derivatives in a one-pot procedure. - In: Tetrahedron letters, ISSN 1873-3581, Bd. 52 (2011), 29, S. 3814-3817

http://dx.doi.org/10.1016/j.tetlet.2011.05.067
Schütze, Christina; Ritter, Uwe; Scharff, Peter; Fernekorn, Uta; Prylutska, Svitlana; Bychko, Andriy; Rybalchenko, Volodymyr; Prylutskyy, Yurij
Interaction of N-fluorescein-5-isothiocyanate pyrrolidine-C60 with a bimolecular lipid model membrane. - In: Materials science & engineering, ISSN 1873-0191, Bd. 31 (2011), 5, S. 1148-1150

http://dx.doi.org/10.1016/j.msec.2011.02.026
Knauer, Andrea; Thete, Aniket; Li, Shuning; Romanus, Henry; Csáki, Andrea; Fritzsche, Wolfgang; Köhler, Michael
Au/Ag/Au double shell nanoparticles with narrow size distribution obtained by continuous micro segmented flow synthesis. - In: The chemical engineering journal, ISSN 1873-3212, Bd. 166 (2011), 3, S. 1164-1169

http://dx.doi.org/10.1016/j.cej.2010.12.028
Li, Shuning; Groß, Alexander G.; Günther, P. Mike; Köhler, J. Michael
Hydrothermal micro continuous-flow synthesis of spherical, cylinder-, star- and flower-like ZnO microparticles. - In: The chemical engineering journal, ISSN 1873-3212, Bd. 167 (2011), 2/3, S. 681-687

http://dx.doi.org/10.1016/j.cej.2010.09.083
Abahmane, Lahbib; Knauer, Andrea; Köhler, Michael; Groß, Gregor Alexander
Synthesis of polypyridine derivatives using alumina supported gold nanoparticles under micro continuous flow conditions. - In: The chemical engineering journal, ISSN 1873-3212, Bd. 167 (2011), 2/3, S. 519-526

http://dx.doi.org/10.1016/j.cej.2010.08.078
Köhler, J. Michael; Möller, Frances; Schneider, Steffen; Günther, P. Mike; Albrecht, Arne; Groß, Alexander G.
Size-tuning of monodisperse PMMA nanoparticles by micro-continuous-flow polymerization using a silicon micro-nozzle array. - In: The chemical engineering journal, ISSN 1873-3212, Bd. 167 (2011), 2/3, S. 688-693

http://dx.doi.org/10.1016/j.cej.2010.09.079
Koehler, Michael; Köhler, Michael;
Vom Urknall zum Cyberspace : fast alles über Mensch, Natur und Universum. - Weinheim : Wiley-VCH-Verl., 2011. - XIV, 216 S.. - (Erlebnis Wissenschaft) ISBN 978-3-527-32739-3
Literaturangaben S. 215-216

Fernekorn, Uta; Hampl, Jörg; Hildmann, Christian; Weise, Frank; Klett, Maren; Läffert, Annette; Schober, Andreas
Untersuchung allgemeiner Kultivierungsparameter von HepG2 Zellen in polymerbasierten, mikrostrukturierten Tellträgern. - In: Biomaterialien, ISSN 2191-4672, Bd. 11 (2010), 1, S. 99

https://doi.org/10.1515/BIOMAT.2010.11.1.51