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Chao, Xin; Yan, Chengzhan; Zhao, Huaping; Wang, Zhijie; Lei, Yong
Micro-nano structural electrode architecture for high power energy storage. - In: Journal of semiconductors, ISSN 2058-6140, Bd. 44 (2023), 5, 050201, S. 1-6

https://doi.org/10.1088/1674-4926/44/5/050201
Jäger, Max; Helbig, Thomas; Goos, Moritz; Köhring, Sebastian; Witte, Hartmut
Characterization of an antagonistic actuation system with nonlinear compliance for an upper-arm exoskeleton. - In: Actuators, ISSN 2076-0825, Bd. 12 (2023), 5, 196, S. 1-24

The parallel connection of technical and biological systems with a comparable mechanical behavior offers the possibility of reducing the interaction forces between those systems. Especially in the context of human-robot interaction (e.g., exoskeletons), it can improve user safety and acceptance at the same time. With this aim, we used antagonistic actuators with nonlinear compliance for a modular upper-extremity exoskeleton following biological paragons, mirroring the “blueprint” of its human user. In a test-bed setup, we compared antagonistic compliant actuation with antagonistic stiff, unilateral stiff and unilateral compliant actuation in the artificial “elbow joint” of the exoskeleton test bed. We show that this type of actuation allows the variation of the joint stiffness during motion, independent of the position. With the approach we propose, compliance leads to reduced force peaks and angular jerk, without sacrifices in terms of time constants and overshoot of amplitudes. We conclude that the presented actuation principle has considerable benefits in comparison to other types of exoskeleton actuation, even when using only commercially available and 3D printed components. Based on our work, further investigations into the control of compliant antagonistically actuated exoskeletons become realizable.



https://doi.org/10.3390/act12050196
Marquardt, Richard; Zahari, Finn; Carstensen, Jürgen; Popkirov, George; Gronenberg, Ole; Kolhatkar, Gitanjali; Kohlstedt, Hermann; Ziegler, Martin
Impedance spectroscopy on hafnium oxide-based memristive devices. - In: Advanced electronic materials, ISSN 2199-160X, Bd. 9 (2023), 6, 2201227, S. 1-14

Memristive devices for neuromorphic computing have been attracting ever growing attention over the last couple of years. In neuromorphic electronics, memristive devices with multi-level resistance states are required to accurately reproduce synaptic weights. Here, a memristive device based on a multilayer oxide system (Nb/NbOx/Al2O3/HfO2/Au), which features a filamentary-free, homogenous interfacial resistive switching mechanism, is investigated. To gain a deeper insight into the switching mechanism, impedance spectroscopy (ImpSpec), X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM) are exploited. While this work focuses on the analysis of impedance and current-voltage characteristics, XPS and TEM investigations can be found in a companion paper (Zahari et al.). In the course of this investigation, potentiodynamic impedance spectroscopy (PD-ImpSpec) and time resolved impedance spectroscopy (TR-ImpSpec) in combination with transient analysis are used. Evidence is presented of switching kinetics at voltages above 2.1 V directly related to changes in Schottky barrier resistance. These switching kinetics can in turn be interpreted by the charging and discharging of double positively charged oxygen vacancies VO+2$\bf V_\bf O^\bm + 2$ ≈ 0.9 eV. The results of the impedance analysis are translated into a more general model for memristive devices to map the physical processes during switching.



https://doi.org/10.1002/aelm.202201227
Zahari, Finn; Marquardt, Richard; Kalläne, Matthias; Gronenberg, Ole; Schlueter, Christoph; Matveyev, Yury; Haberfehlner, Georg; Diekmann, Florian; Nierhauve, Alena; Buck, Jens; Hanff, Arndt; Kolhatkar, Gitanjali; Kothleitner, Gerald; Kienle, Lorenz; Ziegler, Martin; Carstensen, Jürgen; Roßnagel, Kai; Kohlstedt, Hermann
Trap-assisted memristive switching in HfO2-based devices studied by in situ soft and hard X-ray photoelectron spectroscopy. - In: Advanced electronic materials, ISSN 2199-160X, Bd. 9 (2023), 6, 2201226, S. 1-17

Memristive devices are under intense development as non-volatile memory elements for extending the computing capabilities of traditional silicon technology by enabling novel computing primitives. In this respect, interface-based memristive devices are promising candidates to emulate synaptic functionalities in neuromorphic circuits aiming to replicate the information processing of nervous systems. A device composed of Nb/NbOx/Al2O3/HfO2/Au that shows promising features like analog switching, no electro-forming, and high current-voltage non-linearity is reported. Synchrotron-based X-ray photoelectron spectroscopy and depth-dependent hard X-ray photoelectron spectroscopy are used to probe in situ different resistance states and thus the origin of memristive switching. Spectroscopic evidence for memristive switching based on the charge state of electron traps within HfO2 is found. Electron energy loss spectroscopy and transmission electron microscopy support the analysis. A device model is proposed that considers a two-terminal metal-insulator-semiconductor structure in which traps within the insulator (HfO2/Al2O3) modulate the space charge region within the semiconductor (NbOx) and, thereby, the overall resistance. The experimental findings are in line with impedance spectroscopy data reported in the companion paper (Marquardt et al). Both works complement one another to derive a detailed device model, which helps to engineer device performance and integrate devices into silicon technology.



https://doi.org/10.1002/aelm.202201226
Adamopoulos, Nikolaos D.; Tsierkezos, Nikos; Ntziouni, Afroditi; Zhang, Fu; Terrones, Mauricio; Kordatos, Konstantinos V.
Synthesis, characterization, and electrochemical performance of reduced graphene oxide decorated with Ag, ZnO, and AgZnO nanoparticles. - In: Carbon, ISSN 1873-3891, Bd. 213 (2023), 118178

Graphene oxide (GO) derived from the oxidization of graphite exhibits high specific surface area with potential in electrochemical applications. Furthermore, silver and zinc oxide nanoparticles, further denoted as AgNPs and ZnONPs, respectively, display superior physicochemical and electronic properties, that would significantly improve the electrocatalytic properties by being applied in electrochemical sensing. Consequently, in the present work, three different hybrid nanomaterials consisting of reduced graphene oxide (rGO) modified with either AgNPs, ZnONPs, or combined AgZnONPs were synthesized and characterized. The synthesis of GO was performed by a modified Hummer's method, while the decoration of GO with the nanoparticles was carried out by self-assembly solvothermal processes. The Ag-rGO, ZnO-rGO, and AgZnO-rGO nanocomposite hybrid materials were characterized by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), Raman spectroscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) combined with energy-dispersive X-ray spectroscopy (EDX). Furthermore, the electrochemical responses of the fabricated nanocomposites towards the standard ferrocyanide/ferricyanide [Fe(CN)6]3-/4- redox system were investigated using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques. The results have been explained in terms of structural differences between the nanoparticles formed on the surface of the fabricated nanocomposite materials. Namely, the improved electrochemical performance of ZnO-rGO can be attributed to the high surface to volume ratio of ZnO, which provides greater area of electrode/electrolyte junction and consequently, large number of sites at the electrolyte-ZnO interface. The aim of the present work is the fabrication of novel high-performance rGO-based nanomaterials for applications in electrochemical sensing.



https://doi.org/10.1016/j.carbon.2023.118178
Gravelle, Simon; Haber-Pohlmeier, Sabina; Mattea, Carlos; Stapf, Siegfried; Holm, Christian; Schlaich, Alexander
NMR investigation of water in salt crusts: insights from experiments and molecular simulations. - In: Langmuir, ISSN 1520-5827, Bd. 39 (2023), 22, S. 7548-7556

The evaporation of water from bare soil is often accompanied by the formation of a layer of crystallized salt, a process that must be understood in order to address the issue of soil salinization. Here, we use nuclear magnetic relaxation dispersion measurements to better understand the dynamic properties of water within two types of salt crusts: sodium chloride (NaCl) and sodium sulfate (Na2SO4). Our experimental results display a stronger dispersion of the relaxation time T1 with frequency for the case of sodium sulfate as compared to sodium chloride salt crusts. To gain insight into these results, we perform molecular dynamics simulations of salt solutions confined within slit nanopores made of either NaCl or Na2SO4. We find a strong dependence of the value of the relaxation time T1 on pore size and salt concentration. Our simulations reveal the complex interplay between the adsorption of ions at the solid surface, the structure of water near the interface, and the dispersion of T1 at low frequency, which we attribute to adsorption-desorption events.



https://doi.org/10.1021/acs.langmuir.3c00036
Hu, Ping; Dong, Yulian; Yang, Guowei; Chao, Xin; He, Shijiang; Zhao, Huaping; Fu, Qun; Lei, Yong
Hollow CuSbSy coated by nitrogen-doped carbon as anode electrode for high-performance potassium-ion storage. - In: Batteries, ISSN 2313-0105, Bd. 9 (2023), 5, 238, S. 1-15

As a potential anode material for potassium-ion batteries (PIBs), bimetallic sulfides are favored by researchers for their high specific capacity, low cost, and long cycle life. However, the non-ideal diffusion rate and poor cycle stability pose significant challenges in practical applications. In this work, bimetallic sulfide CuSbSyC with a yolk-shell structure was synthesized by in situ precipitation and carbonization. When CuSbSy is applied in the anode of PIBs, it can provide the desired capacity and reduce the volume expansion of the compound through the synergistic effect between copper and antimony. At the same time, the existence of the nitrogen-doped carbon shell confines the material within the shell while improving its electrical conductivity, inhibiting its volume expansion and aggregation. Therefore, CuSbSy@C exhibits a satisfactory capacity (438.8 mAh g^-1 at 100 mA g^-1 after 60 cycles) and an excellent long cycle life (174.5 mAh g^-1 at 1000 mA g^-1 after 1000 cycles).



https://doi.org/10.3390/batteries9050238
Heiniger-Schell, Juliana; Bharuth-Ram, Krish; Naicker, Kimara; Masondo, Vusumuzi; Dang, Thien Thanh; Escobar Castillo, Marianela; Díaz-Guerra, Carlos; Marschick, Georg; Masenda, Hilary; Gunnlaugsson, Haraldur P.; Qi, Bingcui; Unzueta, Iraultza; Ólafsson, Sveinn; Adhikari, Rajdeep; Peters, Gerrard; Naidoo, Deena; Schaaf, Peter; Zyabkin, Dmitry; Johnston, Karl; Becker, Sven; Jakob, Gerhard
Temperature dependence of the hyperfine magnetic field at Fe sites in Ba-doped BiFeO3 thin films studied by emission Mössbauer spectroscopy. - In: Crystals, ISSN 2073-4352, Bd. 13 (2023), 5, 724, S. 1-13

Emission 57Fe Mössbauer spectroscopy (eMS), following the implantation of radioactive 57Mn+ ions, has been used to study the temperature dependence of the hyperfine magnetic field at Fe sites in Ba-doped BiFeO3 (BFO) thin films. 57Mn β decays (t1/2 = 90 s) to the 14.4 keV Mössbauer state of 57Fe, thus allowing online eMS measurements at a selection of sample temperatures during Mn implantation. The eMS measurements were performed on two thin film BFO samples, 88 nm and 300 nm thick, and doped to 15% with Ba ions. The samples were prepared by pulsed laser deposition on SrTiO3 substrates. X-ray diffraction analyses of the samples showed that the films grew in a tetragonal distorted structure. The Mössbauer spectra of the two films, measured at absorber temperatures in the range 301 K-700 K, comprised a central pair of paramagnetic doublets and a magnetic sextet feature in the wings. The magnetic component was resolved into (i) a component attributed to hyperfine interactions at Fe3+ ions located in octahedral sites (Bhf); and (ii) to Fe3+ ions in implantation induced lattice defects, which were characterized by a distribution of the magnetic field BDistr. The hyperfine magnetic field at the Fe probes in the octahedral site has a room temperature value of Bhf = 44.5(9) T. At higher sample temperatures, the Bhf becomes much weaker, with the Fe3+ hyperfine magnetic contribution disappearing above 700 K. Simultaneous analysis of the Ba-BFO eMS spectra shows that the variation of the hyperfine field with temperature follows the Brillouin curve for S = 5/2.



https://doi.org/10.3390/cryst13050724
Stricklin, Isaac; Gotszalk, Teodor; Behzadirad, Mahmoud; Manske, Eberhard; Kissinger, Thomas; Rangelow, Ivo W.; Busani, Tito L.
Multipurpose active scanning probe cantilevers for near-field spectroscopy, scanning tunnel imaging, and atomic-resolution lithography. - In: Journal of vacuum science & technology, ISSN 2166-2754, Bd. 41 (2023), 4, S. 042601-1-042601-9

In this work, we report progress on developing a multipurpose scanning probe cantilever applying gallium nitride nanowires as the probe tip. Gallium nitride nanowires possess high potential as probes due to their straight profile, tunable electrical and optical properties, high Young’s Modulus, durability, and high-yield fabrication process. Their wide bandgap enables them to be pumped to emit ultraviolet pulses which can be used for optical imaging and spectroscopy. They can be doped during growth to be electrically conductive, and their sharp tips obtained during epitaxial growth enable confinement of a high electric field at tip-sample interface. Their sharp tips are obtained during fabrication by their epitaxial growth which eliminates the need for postprocess sharpening that is typically required for standard STM tips. We present results of using gallium nitride nanowires for scanning tunnel microscopy applications of atomic-resolution imaging and lithography, and atomic force microscopy applications of imaging and lithography in vacuum and atmospheric environments.



https://doi.org/10.1116/6.0002486
Brachvogel, Marius; Niestroj, Michael; Meurer, Michael; Hasnain, Syed N.; Stephan, Ralf; Hein, Matthias
Space-time adaptive processing as a solution for mitigating interference using spatially-distributed antenna arrays. - In: Navigation, ISSN 2161-4296, Bd. 70 (2023), 3, navi.592, insges. 23 S.

Antenna arrays and spatial processing techniques are among the most effective countermeasures against interference. Here, we demonstrate a new array concept consisting of spatially-distributed subarrays that are small enough to fit inside the non-metallic parts of an automobile. This will facilitate concealed installation of these devices in bumpers or side mirrors, which is a strict requirement of the industry and preferred by the customers. Using beamforming algorithms, this array was proven to be robust against jammers in the L1 band. The large distances between the individual antenna elements resulted in a non-negligible baseband delay that violated the narrowband assumption and increased with bandwidth. Hence, this paper demonstrates the influence of a jammer in the L5 band. Space-time adaptive processing that allows for compensation of the delays was introduced and analyzed. Improvements in interference mitigation capabilities were assessed and compared to those of pure spatial state-of-the-art implementation. Real-life measurement data was used to ensure realistic results.



https://doi.org/10.33012/navi.592