Zeitschriftenaufsätze

Rechargeable Na-CO2 batteries are considered to be an effective way to address the energy crisis and greenhouse effect due to their dual functions of CO2 fixation/utilization and energy storage. However, the insolubility and irreversibility of solid discharge products lead to poor discharge capacity and poor cycle performance. Herein, a novel strategy is proposed to enhance the electrochemical performance of hybrid Na-CO2 batteries, using water-in-salt electrolyte (WiSE) to establish an optimal reaction environment, regulate the CO2 reduction pathway, and ultimately convert the discharge product of the battery from Na2CO3 to formic acid (HCOOH). This strategy effectively resolves the issue of poor reversibility, allowing the battery to exhibit excellent cycle performance (over 1200 cycles at 30 ˚C), especially under low-temperature conditions (2534 cycles at −20 ˚C). Furthermore, density functional theory (DFT) calculations and experiments indicate that by adjusting the relative concentration of H/O atoms at the electrolyte/catalyst interface, the CO2 reduction pathway in the battery can be regulated, thus effectively enhancing CO2 capture capability and consequently achieving an ultra-high discharge specific capacity of 148.1 mAh cm−2. This work effectively promotes the practical application of hybrid Na-CO2 batteries and shall provide a guidance for converting CO2 into products with high-value-added chemicals.

The 100 Tm superconducting synchrotron SIS100 is the main accelerator of the international Facility for Antiproton and Ion Research (FAIR) currently under advanced construction in Darmstadt, Germany. The SIS100 dipole circuit which creates the magnetic field required to bend the beam, consists of 108 dipoles distributed over six arc sections of the ring. The magnetic field for the beam focusing is generated by three individual quadrupole circuits with total amount of 166 magnets located in both arc and straight sections of the ring. The dipole circuit is powered from two synchronized power converters and will be cycled up to 13.2 kA at 28 kA/s. The dipole magnet chain is not self-protecting. 12 energy extraction resistors are used to protect the superconducting coils and bus-bars against overheating and overvoltage in case of a quench. The largest quadrupole circuit consists of 83 magnets. The nominal current is 10.5 kA cycled up to 22 kA/s. Similarly to dipoles, the quadrupole circuit is not self-protecting. Four energy extraction units are used to discharge the circuit's energy in case of a quench or fast power abort. This work presents a customized Python software tool created to simulate electrical behavior of a superconducting magnet chain. The software is under development at GSI. However, certain modules strongly rely on the approach developed at CERN. The paper contains selected simulations of the SIS100 dipole and defocusing quadrupole circuits. Special attention is drawn to: transient effects during typical operation and during the fast power abort; the damping effect of vacuum chambers; voltage distribution in the circuits and basic failure modes.

Bio-inspired algorithms and architectures are considered superior to classical architectures for certain applications. An important aspect with regard to the function of the human memory is the sorting according to important and unimportant experiences. Certain important experiences are stored significantly longer than less important ones. One criterion to make this distinction is the frequency of occurrence of a property. In this work an RSFQ circuit is presented, which performs this weighting in the learning process of a synapse. In a simulation study, the principle of the selective learning mechanism is shown to work and a variant of permanent memory is demonstrated.

Our previous study (Zheng et al 2020 Metall. Mater. Trans. B 51 558–69; Zheng et al 2020 Acta Metall. Sin.56 929–36) reports a non-invasive in-situ measurement technology using Lorentz force velocimetry (LFV) to quantitatively measure the meniscus velocity of molten steel online. However, effective signal recognition from complex environment noise and determination of zero-point calibration in harsh metallurgical processing is an essentially challenging task and indeed needs further exploration. In this paper, a method of combining double probe arrangement with real-time differential processing technology was proposed, the twin design structure not only enables the measurement of ∼mN Lorentz forces, but also has significant characteristics of environmental tolerance. The Lorentz force signal caused by conductor motion can be accurately calculated through a differential method, meaning that the problem of zero compensation in industrial online measurement can be effectively overcome. Moreover, based on the functional correlation between the Lorentz force and the parameter of the conductor to be measured, a method of the probes moving variably and actively and their data difference ratio processing was adopted, so as to achieve dynamic calibration during online measurement. This measurement strategy provides a new approach for LFV to achieve online dynamic measurement and online calibration, and provides technical support for electromagnetic measurement technology towards engineering applications.

Plastics are versatile materials, offering lightweight, durable, and affordable solutions across various industries. However, their non-degradable nature poses challenges by end of their life. This study presented an innovative carbonyl extraction method to utilize waste poly(bisphenol A carbonate) (PC) as reaction precursor to synthesis of activated furan as precursor for photoswitchable Stenhouse adducts. This innovative chemical strategy not only generated N,N’-functionalized barbiturates but also provided an eco-friendly and cost-effective alternative to traditional synthesis methods. The method presented hereby not only promotes sustainability by repurposing waste polycarbonate as carbonyl equivalent under green conditions but also yielded reusable bisphenol A (BPA). Furthermore, the derived activated furans exhibited their functionality by forming colored donor-acceptor Stenhouse adducts (DASAs) on aminated polymer surfaces. This work demonstrated a transition from a linear plastics economy toward a circular one, highlighting the potential of plastic waste as a resource for creating materials with improved properties.