Zeitschriftenaufsätze

Assessments of source reconstruction procedures in electroencephalography and computations of transcranial electrical stimulation profiles require verification and validation with the help of ground truth configurations as implemented by physical head phantoms. For these phantoms, synthetic materials are needed, which are mechanically and electrochemically stable and possess conductivity values similar to the modeled human head tissues. Three-compartment head models comprise a scalp layer with a conductivity range of 0.137 S/m to 2.1 S/m, a skull layer with conductivity values between 0.066 S/m and 0.00275 S/m, and an intracranial volume with an often-used average conductivity value of 0.33 S/m. To establish a realistically shaped physical head phantom with a well-defined volume conduction configuration, we here characterize the electrical conductivity of synthetic materials for modeling head compartments. We analyzed agarose hydrogel, gypsum, and sodium chloride (NaCl) solution as surrogate materials for scalp, skull, and intracranial volume. We measured the impedance of all materials when immersed in NaCl solution using a four-electrode setup. The measured impedance values were used to calculate the electrical conductivity values of each material. Further, the conductivities in the longitudinal and transverse directions of reed sticks immersed in NaCl solution were measured to test their suitability for mimicking the anisotropic conductivity of white matter tracts.

Lifecycle assessments suggest preventing halogenated solvents or solvent additives for environmentally friendly polymer solar cells. Thus, the active layers of polymer:fullerene bulk heterojunction solar cells based on poly[4,8-bis-(2-ethyl-hexyl-thiophene-5-yl)-benzo[1,2-b:4,5-b0]dithiophene-2,6-diyl]-alt-[2-(20-ethyl-hexanoyl)-thieno[3,4-b]thiophen-4,6-diyl] (PBDTTT-CT) and the fullerene derivative [6,6]-phenyl-C70-butyric acid methyl ester (PC70BM) are cast from m-xylene solutions. Ortho-vanilline is used as a nonhazardous and nontoxic solvent additive. Completed photovoltaic devices are subjected to accelerated laboratory weathering tests. Photovoltaic parameters are periodically obtained from current-voltage recordings of the solar cells twice an hour under well-defined aging conditions following the International Summit on Organic Photovoltaic Stability (ISOS) protocols. An analysis of aging kinetics reveals the superposition of two individual degradation mechanisms, of which one is assigned to continued intermixing and the other one to the formation of a blocking layer by interfacial segregation.

Purpose The purpose of this paper is to present the advantageous applicability of the bicomplex analysis in the context of the Finite Element Method (FEM). This method can be applied for wave propagation problems in various environments. Design/methodology/approach In this paper, the bicomplex number system is introduced and accordingly the differential equation for time-harmonic Maxwell’s equations in homogeneous media is derived in detail. Besides that, numerical simulations of wave propagation are performed and compared to the traditional approach based on classical FEM related to the Helmholtz equation. The appropriate error norm is investigated for different discretizations. Findings The results show that the use of bicomplex analysis in FEM leads to the higher accuracy of the electromagnetic field determination compared to the traditional Helmholtz approach. By using the bicomplex-valued formulation, the complex-valued electric and magnetic fields can be found directly and no additional FEM calculations are necessary to get the whole field. Originality/value The direct bicomplex formulation overcomes the use of the second order derivatives, which leads to the higher accuracy. In general, accurate calculations of the wave propagation in FEM is still an open problem and the approach described in this paper is a contribution to this class of problems.

Varying compliance (VC) is an unavoidable form of parametric excitation in rolling bearings and can affect the stability and safety of the bearing and its supporting rotor system. To date, we have investigated VC primary resonance in ball bearings, and in this paper other parametric VC resonance types are addressed. For a classical ball bearing model with Hertzian contact and clearance nonlinearities between the rolling elements and raceway, the harmonic balance and alternating frequency/time domain (HB-AFT) method and Floquet theory are adopted to analyze the VC parametric resonances and their stabilities. It is found that the 1/2-order subharmonic resonances, 2-order superharmonic resonances, and various VC combination resonances, such as the 1-order and 2-order summed types, can be excited, thus resulting in period-1, period-2, period-4, period-8, period-35, quasi-period, and even chaotic VC motions in the system. Furthermore, the bifurcation and hysteresis characteristics of complex VC resonant responses are discussed, in which cyclic fold, period doubling, and the second Hopf bifurcation can occur. Finally, the global involution of VC resonances around bearing clearance-free operations (i.e., adjusting the bearing clearance to zero or one with low interference) are provided. The overall results extend the investigation of VC parametric resonance cases in rolling bearings.

Particulate polymers at the nanoscale are exceedingly promising for diversified functional applications ranging from biomedical and energy to sensing, labeling, and catalysis. Tailored structural features (i.e., size, shape, morphology, internal softness, interior cross-linking, etc.) determine polymer nanoparticles' impact on the cargo loading capacity and controlled/sustained release, possibility of endocytosis, degradability, and photostability. The designed interfacial features, however (i.e., stimuli-responsive surfaces, wrinkling, surface porosity, shell-layer swellability, layer-by-layer surface functionalization, surface charge, etc.), regulate nanoparticles interfacial interactions, controlled assembly, movement and collision, and compatibility with the surroundings (e.g., solvent and biological environments). These features define nanoparticles' overall properties/functions on the basis of homogeneity, stability, interfacial tension, and minimization of the surface energy barrier. Lowering of the resultant outcomes is directly influenced by inhomogeneity in the structural and interfacial design through the structure-function relationship. Therefore, a key requirement is to produce well-defined polymer nanoparticles with controlled characteristics. Polymers are amorphous, flexible, and soft, and hence controlling their structural/interfacial features through the single-step process is a challenge. The microfluidics reaction strategy is very promising because of its wide range of advantages such as efficient reactant mixing and fast phase transfer. Overall, this feature article highlights the state-of-the-art synthetic features of polymer nanoparticles with perspectives on their advanced applications.