Zeitschriftenaufsätze

Renewable fuel generation is essential for a low carbon footprint economy. Thus, over the last five decades, a significant effort has been dedicated towards increasing the performance of solar fuels generating devices. Specifically, the solar to hydrogen efficiency of photoelectrochemical cells has progressed steadily towards its fundamental limit, and the faradaic efficiency towards valuable products in CO2 reduction systems has increased dramatically. However, there are still numerous scientific and engineering challenges that must be overcame in order to turn solar fuels into a viable technology. At the electrode and device level, the conversion efficiency, stability and products selectivity must be increased significantly. Meanwhile, these performance metrics must be maintained when scaling up devices and systems while maintaining an acceptable cost and carbon footprint. This roadmap surveys different aspects of this endeavor: system benchmarking, device scaling, various approaches for photoelectrodes design, materials discovery, and catalysis. Each of the sections in the roadmap focuses on a single topic, discussing the state of the art, the key challenges and advancements required to meet them. The roadmap can be used as a guide for researchers and funding agencies highlighting the most pressing needs of the field.

The deuteron transverse relaxation properties of polyethylene oxide melts of four different molecular weights, covering the range from the onset of entanglements to the regime of fully entangled chains, are investigated using Hahn echo decays over an extensive time interval up to ten times the effective transverse spin relaxation time. The results are compared to predictions based on the Rouse and reptation formalisms, taking into account the dynamical heterogeneity of linear polymer chains produced by the end segments. The experimental results can be described qualitatively by a combination of both models, with the contribution of reptation dynamics increasing with growing chain length. The transition is continuous, rather than being characterized by sharp regime boundaries. Up to a molecular weight of 300.000 g/mol, the predicted limit of pure reptation dynamics is not yet reached. Quantitative deviations from the predicted decays as computed by numerical procedures become observable toward the long-time limit of the Hahn echo decays and are being discussed in terms of shortcomings of the available reptation theories.

Profound understanding of the local electronic and defect structure in semiconductors always plays a vital role in the further developing of applications of such materials. In the present work an investigation of the electronic structure in hydrogenated TiO2 (rutile) thin films is conducted by virtue of Time-Differential γ-γ Perturbed Angular Correlation spectroscopy (TDPAC or PAC) with 111mCd/Cd isotope, produced and implanted at ISOLDE/CERN. The measurements were performed at 581 K as a function of the temperature of the samples during hydrogenation. Despite the fact, that rutile single crystals usually show the presence of two local environments, when are studies with Cd/In isotopes, the current pristine thin films sample had a single electric field gradient. Upon various degrees of hydrogenation, Cd probe atoms showed underwent alterations, resulting in up to 3 different local surroundings, generally with high electric field gradients. Broad EFG distributions are likely due to randomly distributed point defects in the neighbourhood of Cd acceptors. Observed results suggest that hydrogenations performed at RT and 423 K are not able to promote unique defect configurations, while in the range of 473-573 K the formation of such configurations is observed. Therefore, one may assume that the formation of Cd-defect complexes (Cd-H pairs) is temperature enhanced. At higher levels of hydrogenation (663 K), the samples become partly amorphous that further hinders any atomistic studies with strong damped PAC spectra. Cd-H complexes seem to be stable up to annealing up to 581 K annealing. The obtained results give a deep insight into complex hydrogen defects, their interactions and bond formations with Cd acceptor.

The design of compliant mechanisms is a much more complicated task than their analysis. Consequently, there are many more methods available for the analysis of compliant mechanisms than for their synthesis. In this article, a contribution to the synthesis of compliant mechanisms is made by presenting a comparison of two different methods for their design. In both methods rigid-body systems are used as a basis for compliant mechanisms. Depending on the task of the compliant mechanism, one of these methods can be selected and applied. The deviations between the results of the used theory and measurement results as well as FEM results are less than 5.5 % for displacements and acting forces. Selected mechanisms for the realization of a straight-line motion of a point and for given relative motions are presented as examples.

It is well known that tunable lenses, with refractive power that can be varied, e.g., by changing the curvature of a membrane, can replace the motion of lens groups in zoom systems. Similar to classical zoom systems, the performance of these systems is heavily influenced by the fundamental first-order layout. Moreover, the first-order layout sets the most important requirements for the employed tunable lenses. In this contribution, we present a method for the analysis of a large number of possible first-order solutions for typical requirements and for the selection of the most promising layouts. The first-order solution space is mapped, allowing the layouts to be automatically filtered and plotted depending on pre-defined characteristics. Ray tracing of the marginal and chief rays combined with the traditional thin lens aberration theory provide efficient estimations of the expected installation space requirements and performance for each first-order layout. Using an example, we demonstrate good agreement between these estimations and the corresponding real lens layout, optimized by commercial raytracing software. The presented design method for zoom systems based on tunable lenses is compared with similar approaches for classical zoom lenses.